Thursday, November 29, 2007 |
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| Chairman:
G. Meyer, Köln |
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| 17:00 |
Gerd Meyer (Köln) |
Opening | |
| K 01 |
17:15 |
Glen. B. Deacon (Monash) |
Rare earths – a source of continuing excitement |
| K 02 |
17:45 |
Paul Maggard, Ling Chen, Laura Castro, Akash Mehta, John D, Corbett (Ames) |
Unusual Condensed Rare-Earth–Transition-Metal
Tellurides and Why Only Certain Rare-Earth Metals Participate |
Friday, November 30, 2007 |
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| Chairman:
R. Kempe, Bayreuth |
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| O 01 |
09:00 |
Tobias Beck , Philip C. Andrews, Benjamin H. Fraser, Peter C. Junk, Massimiliano Massi (Göttingen, Monash) |
Towards a Better Understanding of the Formation
of Lanthanoid Hydroxo Clusters with Chelating Ligands |
| O 02 |
09:20 |
Christian Döring, Winfried Kretschmer, Rhett Kempe (Bayreuth) |
Aminopyridinato ligand stabilized lanthanoid
alkyl complexes used for polymerization reactions |
| O 03 |
09:40 |
Shaozhong Ge, Auke Meetsma, Bart Hessen (Groningen) |
Neutral and Cationic Lanthanide Complex Catalyzed Z-selective Head-to-head Dimerization of (Hetero-)aromatic Terminal Alkynes |
| O 04 |
10:00 |
Christian Ruspic, Sjoerd Harder (Duisburg-Essen) |
Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII |
| O 05 |
10:20 |
Amadou Ndiaye, Fabrice Guyon, Michael Knorr, Volker Huch, Michael Veith (Saarbrücken, Besancon) |
Luminescence studies in dithiolene-lanthanide
complexes |
| 10:40 |
Coffee Break | |
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| K 03 |
11:00 |
Arash Babai, Anna Getsis, Bert Mallick, Slawomir Pitula, Sifu Tang, Anja V. Mudring (Bochum) |
Lanthanide based ionic liquids as solvents
for synthesis as well as optical and magnetic applications |
| K 04 |
11:30 |
Peter Nockemann, Ben Thijs, Kyra Lunstroot, Rik Van Deun, Koen Binnemans (Leuven) |
Speciation of Rare-Earth Complexes in Ionic
Liquids |
| 12:00 |
Lunch Break | |
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Chairman:
P. Roesky, Berlin |
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| K 05 |
13:00 |
Peter C. Junk (Monash) |
Access to heterobimetallic complexes by the direct route |
| O 06 |
13:30 |
Glen B. Deacon, Peter C. Junk, Graeme J. Moxey (Monash) |
Synthesis and Structural Characterisation
of Bi-metallic Aryloxide Complexes |
| O 07 |
13:50 |
Michèle Schappacher, Paul Dessuge, Noémi Barros, Laurent Maron, Sophie M. Guillaume (Pessac, Toulouse, Rennes) |
MMA Polymerisation initiated by rare earth
(boro)hydride complexes: a combined experimental and computational approach |
| O 08 |
14:10 |
Hellen E Dyer, Philip Mountford (Oxford) |
Borohydride and zwitterionic bis(phenolate)amine lanthanide complexes for the ring-opening polymerisation of cyclic esters |
| O 09 |
14:30 |
Ian J. Casely, Polly L. Arnold (Edinburgh) |
Tetravalent cerium carbene complexes |
| O 10 |
14:50 |
Mathias U. Kramer, Thomas P. Spaniol, Jun Okuda (Aachen) |
Searching for New Organolanthanide Starting Materials |
| 15:10 |
Coffee Break and Poster Session |
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Chairman:
H. Schumann, Berlin |
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| O 11 |
16:00 |
Olga Osetska, Markus Albrecht, Roland Fröhlich, Jean-Claude G. Bünzli, Annina Aebischer, (Aachen, Münster, Lausanne) |
Sensitization of NIR Luminescence from the
Mono- and Dinuclear Ln3+ Complexes by Energy Transfer from
8-Hydroxyquinoline Ligands |
| O 12 |
16:20 |
Michaël Terrier, Philippe Zinck, Thomas Chenal, André Mortreux, Marc Visseaux (Villeneuve) |
Lanthanide Trisborohydrides as valuable
precursors for organometallic synthesis |
| O 13 |
16:40 |
Hanne-M. Sommerfeldt, Christian Meermann, Karl W. Törnroos, Reiner Anwander (Bergen) |
Reactivity of Peralkylated LnIIAlIII
Heterobimetallic Complexes toward N/O Donor Molecules and HC5Me5 |
| K 06 |
17:00 |
François Nief (Palaiseau) |
Synthesis and reactivity of divalent thulium, dysprosium and neodymium organometallics |
| K 07 |
17:30 |
Peter W. Roesky (Berlin) |
Bis(phosphinimino)methanides as Ligands in Lanthanide Chemistry |
| 18:00 |
Terrae Rarae 2007 Award Session Conference Dinner |
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Saturday, December 1, 2007 |
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| Chairman:
T. Schleid, Stuttgart |
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| K 08 |
08:30 |
Karl Krämer, Lukas Keller (Bern, Zürich) |
High Temperature Phase and Thermal Expansion
of PrBr3 |
| K 09 |
09:00 |
Petra Becker, Ladislav Bohatý, Alexander A. Kaminskii (Köln, Moscow) |
Crystal growth and optical properties of
LaBO2MoO4 |
| O 14 |
09:30 |
Christoph J. Höller, Klaus Müller-Buschbaum (München) |
Melt Synthesis – a Suitable Way to Solvent
Free 3-Dimensional RE-Nitrile-Networks |
| O 15 |
09:50 |
Frederick Casper, Claudia Felser (Mainz) |
Magnetic and electronic properties or RENiBi (RE=Pr, Sm, Gd - Tm, Lu) compounds |
| O 16 |
10:10 |
Henning A. Höppe, (Freiburg) |
The Behaviour of Incommensurately Modulated Ln(PO3)3 (Ln = Tb…Yb, Y) at Low Temperatures |
| 10:30 |
Coffee Break | |
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| O 17 |
11:00 |
Dominique Robert, Thomas P. Spaniol, Jun Okuda (Aachen) |
Cationic Allyl Complexes of Rare-Earth Metals |
| O 18 |
11:20 |
Melanie Zimmermann, Helmut Sitzmann, Karl W. Törnroos, Reiner Anwander (Bergen, Kaiserslautern) |
Living trans-1,4 Isoprene Polymerization
by Cationic Rare-Earth Metal Half-Sandwich Complexes |
| O 19 |
11:40 |
Winfried P. Kretschmer, Sérgio Bambirra, Nicky Philipp, Auke Meetsma, Bart Hessen, Christian Döring, Rhett Kempe (Groningen, Bayreuth) |
Reactivity control of tri-alkyl rare-earth
metal complexes |
| 12:00 |
Lunch The End |
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| P01 | Mareike Ahlers, Mathias Wickleder (Oldenburg) |
THF-Solvates of Rare Earth Perchlorates: Syntheses, Crystal structures and Thermal Behaviour |
| P02 | Sven Arenz, Ralf Giernoth (Köln) |
Structure Determination of Yb(II)-complexes in Solution by the Use of 2-Dimensional-NMR-Spectroscopy |
| P03 | Polly L. Arnold (Edinburgh) |
N-heterocyclic Carbene complexes of lanthanides; redox and reactivity |
| P04 | Jacinta M. Bakker, Mikhail V. Butovskiy, Glen B. Deacon, Peter C. Junk, Rhett Kempe (Monash, Bayreuth) |
Transition metal – Rare Earth bonds |
| P05 | Jacinta M. Bakker, Glen B. Deacon, Peter C. Junk (Monash) |
Rare Earth Thiocyanates |
| P06 | Céline Belot, Laurent Guyard, Volker Huch, Michael Knorr, Michael Veith (Saarbrücken, Besancon) |
Synthesis and crystal structure investigations on trivalent rare earth (Y3+, Nd3+, Er3+, Sm3+) carbinolates containing thienyl substituants |
| P07 | Makram Ben Hamida, Mathias Wickleder (Oldenburg) |
Rare earth selenites containing nickel |
| P08 | Jean-Charles Buffet, Polly L. Arnold (Edinburgh) |
Homochiral metal complexes for biodegradable polymer synthesis |
| P09 | H. L. Cui, Claudia Wickleder (Siegen) |
Optical Properties of Diluted Mixed-Valent Systems |
| P10 | Simmi Datta, Viswanathan Baskar, Li Henan, Peter W. Roesky (Berlin) |
Synthesis and Structural Characterization of Tetranuclear and Pentanuclear Lanthanide Clusters |
| P11 | Kathrin Daub, Gerd Meyer (Köln) |
Dysprosium clusters: Monomers, dimers and chains |
| P12 | Michal Wiecko, Michael T. Gamer, Peter W. Roesky (Berlin) |
Rare Earth / Main Group Metal-to-Metal Bonds |
| P13 | Régis M. Gauvin, Christophe Dujardin (Villeneuve d'Ascq) |
Silica-grafted lanthanide amides: reactions of electrophilic surface species with the inorganic support |
| P14 | Esther M. Jahr, Leena K. Malinen, Raija Oilunkaniemi, Risto S. Laitinen (Oulu) |
Structural elucidation of lanthanide nitrates with 1,10-phenanthroline |
| P15 | Dong-Hee Kang, Thomas Schleid (Stuttgart) |
La3S2Cl2[AsS3]: A Sulfide Chloride Thioarsenate(III) of Lanthanum |
| P16 | Henning A. Höppe, Karolina Kazmierczak, Michi Daub, Manuel C. Bröhmer (Freiburg) |
Coactivation of a-Sr(PO3)2 with Eu2+ and Mn2+ |
| P17 | Winfried P. Kretschmer, Sérgio Bambirra, Edwin Otten, Auke Meetsma, Bart Hessen (Groningen) |
The electronically driven formation of neutral tri-benzyl or anionic tetra-benzyl rare-earth metal complexes |
| P18 | Erwan Le Roux, François Nief, Florian Jaroschik, Karl T. Törnroos, Reiner Anwander (Bergen, Palaiseau) |
Mono-phosphacyclopentadienyl bis(tetramethylaluminate) rare-earth metal complexes |
| P19 | Thomas Linder, Jörg Sundermeyer (Marburg) |
Pentafluorophenylamido complexes of the rare earth metals |
| P20 | Christian Lipp, Thomas Schleid (Stuttgart) |
Er3F[SiO4][SeO3]2: An Erbium Fluoride Oxosilicate Oxoselenate(IV) |
| P21 | Mariana Luna Barros, Robert G. Howe, Cara S. Tredget, Philip Mountford (Oxford) |
New early transition metal chemistry with N3 donor heteroscorpionate ligands |
| P22 | Christian Meermann, Kouji Ohno, Karl W. Törnroos, Kazushi Mashima, Reiner Anwander (Bergen, Osaka) |
Rare-Earth Metal Complexes Bearing Cyclooctatetraenyl and Bis(dimethylsilyamido) Ligands |
| P23 | Nils Meyer, Jelena Jenter, Peter W. Roesky (Berlin) |
Synthesis of Borohydrido Compounds of the Lanthanides |
| P24 | Rafał Janicki, Marcin Sobczyk, Anna Mondry (Wroclaw) |
Spectroscopic investigations of the Eu3+-EDTMP complex in silica - gel matrix |
| P25 | Amadou Ndiaye, Fabrice Guyon, Michael Knorr, Céline Belot, Volker Huch, Michael Veith (Saarbrücken, Besancon) |
Comparative study on lanthanides bearing sulfur-containing ligands: p-p stacking vs steric hindrance |
| P26 | Hyui Sul Lee, Mark Niemeyer (Stuttgart) |
Homo- and heteroleptic lanthanide(II) triazenides |
| P27 | Hyui Sul Lee, Falk Lissner, Regina Stötzel, Claudia Wickleder, Mark Niemeyer (Stuttgart, Siegen) |
Molecular alkaline earth and rare earth metal pentafluoroaryls as precursors for inorganic-organic hybride particles |
| P28 | Nicky Philipp, Winfried P. Kretschmer, Auke Meetsma, Bart Hessen (Groningen) |
Novel yttrium catalysts stabilized by constrained geometry amidinates |
| P29 | Hanns-Dieter Amberger, Hauke Reddmann, William J. Evans (Hamburg, Irvine) |
First parametric analysis of the crystal field splitting pattern of a homoleptic Ln(C5Me5)3 complex: Sm(Cp*)3 |
| P30 | Konstantin A. Rufanov (Moscow) |
Iminophosphoamides of rare earth metals |
| P31 | Marion C. Schäfer, Michaela Laupheimer, Thomas Schleid (Stuttgart) |
Cs3NdSi8O19: A Caesium-Containing Phyllosilicate of Neodymium |
| P32 | Oliver Janka, Thomas Schleid (Stuttgart) |
GdFCl2: The First Fluoride Chloride of the Trivalent Lanthanides |
| P33 | Jean-Marie
Babo, Thomas Schleid (Stuttgart) |
CsCu2Sc3Te6 and CsCuY2Te4: Two New Quaternary Caesium Copper Rare-Earth Metal Tellurides |
| P34 | Jennyfer Sierau, Gerd Meyer (Köln) |
A new rare earth benzoate: Dy(OBz)3 |
| P35 | Marcin Sobczyk (Wroclaw) |
Photoluminescent properties of Eu3+, Eu2+: GdVO4: poly(methyl-methacrylate) nanocomposite |
| P36 | Anke Spannenberg, Bernd H. Müller (Rostock) |
Phosphorus Ylide Complexes of Lanthanides as Catalysts for Ring-Opening Polymerization of Lactones |
| P37 | Michael Rössle, Jens Christoffers, Przemysław Starynowicz (Oldenburg, Wroclaw) |
A complex of Eu(II) with bis-pyridino-18-crown-6 |
| P38 | Alex R. Petrov, O. Thomas, Jörg. Sundermeyer (Marburg) |
Homoleptic Tris-Aryl Complexes of the Rare Earth Metals |
| P39 | Dominique Thielemann, Simmi Datta, Peter W. Roesky (Berlin) |
Chiral and achiral clusters of hydroxo-bridged lanthanides |
| P40 | Andreia Valente, Philippe Zinck, Michael Terrier, André Mortreux, Marc Visseaux (Villeneuve d’Ascq) |
Neodymium-magnesium transmetalation: the first example of a polystyrene catalyzed chain growth |
| P41 | A. Venugopal, T. Pape, A. Willner, N. W. Mitzel (Münster, Bielefeld) |
Utility of N,N-substituted hydroxylamines in rare-earth chemistry |
| P42 | M. J. Vitorino, T. Devic, M. Visseaux (Villeneuve d’Ascq, Versailles) |
Elastomers Nanocomposites by Stereospecific in-situ Polymerization within a Metal-Organic Framework |
| P43 | Mark Vorsthove, Huu Thanh Tran, Ulrich Kynast (Münster) |
Synthesis of YAG:Ce3+ via the Glycothermal method |
| P44 | Christine Walbaum, Ingo Pantenburg, Gerd Meyer (Köln) |
[Gd(OH)(H2O)(B18K6)]I(I3)CH3CN, A New Cationic In-Cavity Complex With Iodide And Triiodide As Anions |
| P45 | Matthias Adlung, Claudia Wickleder (Siegen) |
Luminescence of Divalent Thulium in Chloride Host Lattices |
| P46 | Selvan Demir, Gerd Meyer (Köln) |
Sc{Sc6C}I12 – a rare-earth
metal cluster and its behaviour in solvents |
| P47 | Sonia Gomez Torres, Gerd Meyer (Köln) |
Acetate and Propionate Coordinating Neodymium(III): Nd(OAc)3,
Nd(OAc)3(HOAc)x (x = 2, 4) and Nd(OPr)3(HOPr) |
| P48 | Rannveig Litlabø, Mark Niemeyer, Karl W. Törnroos, Reiner Anwander (Bergen, Mainz) |
Bis(tetramethylaluminate) complexes [NNN]Ln(AlMe4)2 supported by sterically crowded triazenido ligands |
| P49 | Martin Zeuner, Sandro Pagano Wolfgang Schnick (München) |
Precursor Approach towards Lanthanide Dioxy-monocarbodiimides Ln2O2CN2 (Ln = Y, Ho, Er, Yb) employing Insertion of CO2 into organometallic Ln-N Compounds |
| P50 | Adrie J. J. Bos, Pieter Dorenbos, Aurelie Bessiere, B. Viana (Delft, Paris) |
Lanthanide energy levels in YPO4; an example of lanthanide engineering |
| P51 | Patrick J. Eulgem, Axel Klein, Nicola Maggiarosa, Dieter Naumann, Roland W. H. Pohl (Köln) |
New Rare Earth Metal Complexes with Ligands of High Nitrogen
Content |
| P52 | E. van der Kolk, P. Dorenbos (Delft) |
Systematic and material independent variation of electrical, optical, and chemical properties of Ln-materials over the Ln-series (Ln=La,Ce,Pr,..,Lu) |
| P53 | Andreas Krumpel, Erik van der Kolk, Johan de Haas, Pieter Dorenbos, Philippe Boutinaud, Enrico Cavalli, Marco Bettinelli (Delft, Aubière, Parma, Verona) |
Energy level location of tri- and divalent lanthanide cations in LaVO4 |
| P54 | Christian Ruspic, Sjoerd Harder (Duisburg-Essen) |
Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII |
| P55 | Desmond T.C. Ang, Glen B. Deacon, Craig M. Forsyth, Maria Forsyth, Peter C. Junk, Graeme J. Moxey, David R. Turner (Monash) |
Lanthanoid Pyridinecarboxylate Complexes as “Green”
Corrosion Inhibitors |
| P56 | Winicjusz Drozdowski, Pieter Dorenbos (Delft) |
New Rare Earth Based Scintillators |
| P57 | Anthony Chesman, David R. Turner, Boujema Moubaraki, Keith S. Murray, Glen B. Deacon, Stuart R. Batten (Monash) |
Rare Earth and Transition Metal Complexes of Nucleophilic
Addition Products of Dicyanonitrosomethanide |
| P58 | Miroslaw Batentschuk, Farasat Iqbal, Frank Meister, Andres Osvet, Alfons Stiegelschmitt, Martina Weidner, Albrecht Winnacker (Erlangen/Nürnberg) |
Eu2+ luminescence in concentrated Eu-Ca-alumosilicates |
| P59 | Anja Edelmann, Steffen Blaurock, Volker Lorenz, Liane Hilfert, Frank T. Edelmann (Magdeburg) |
Multidecker Sandwich Complexes of Lanthanide Elements |
| P60 | Stephan Gießmann, Anja Edelmann, Steffen Blaurock, Volker Lorenz, Frank T. Edelmann (Magdeburg) |
Heterometallic Disiloxanediolates of Group 3 Elements and Lanthanides - Novel Metallacrowns and Cluster molecules |
| P61 | Peter Dröse, Steffen Blaurock, Volker Lorenz, Frank T. Edelmann (Magdeburg) |
Phenyliodine(III)dichloride - An innovative Reagent for
the Synthesis of Cerium(IV) Complexes |
| P62 | Sina Zimmermann, Gerd Meyer, Frederik Casper, Vadim Ksenofontov, Claudia Felser (Köln, Mainz) |
Scandium Halide Clusters: Structures and Properties |
| P63 | Anna Dietel, Sadaf Qayyum, Kristina Haberland, Rhett Kempe (Bayreuth) |
Low Valent Ytterbium Complexes Stabilized by Sterically Demanding Aminopyridinato Ligands |