Program

Thursday, December 4, 2008
Chairman: Rhett Kempe, Bayreuth
Luminescence
K 01 09:30 Jean-Claude Bünzli
(Lausanne)		 Lanthanide Luminescent Bioprobes for Time-resolved Cell Imaging
K 02 10:10 Matthias Adlung,
Claudia Wickleder
(Siegen)		 Numerous Emission Bands of Tm2+ Ions in Chloride Host Lattices
 
K 03 10:50 Koen Binnemans
(Leuven)		 Luminescence of Lanthanoidmesogenes in the Liquid Crystal State
  11:30   Coffee Break
O 01 12:00 Céline Belot,
Volker Huch,
Michael Veith
(Saarbrücken)		 Synthesis, Crystal Structure, Luminescence and Electrochemical Investigations of Trivalent Rare Earth (Nd3+, Sm3+) Thienyl-Substituted Methoxides
O 02 12:20 Svetlana Eliseeva,
Dmitry Pleshkov,
Konstantin Lyssenko,
Leonid Lepnev,
Natalia Kuzmina
(Moscow)		 Turning of the Luminescent Properties of EuIII and TbIII Hexafluoroacetylacetonates by Insertion of Bidentate O-Donor Ligands
 
O 03 12:40 Lada Puntus
(Moscow)		 Influence of Inner- and Outer-Sphere Bonding Patterns on the LnIII Sensitization in Lanthanide-Containing Compounds and Materials
  13:00   Lunch Break
Chairman: Uwe Ruschwitz, Köln
Solid State
K 04 14:00 John Corbett
(Ames)		 Observations on Structures of and Bonding in a few Rare-Earth-Metal Compounds, both Solid State and Molecular
K 05 14:40 K. Rupprecht,
U. Ponkratz,
O. Leupold,
G. Wortmann
(Paderborn)		 Magnetism and Mixed Valence at Extreme Pressures:  151Eu-NFS Study of EuO, EuS and EuSe up to 120 GPa
 
  15:20   Coffee Break and Poster Session
K 06 16:30 Mathias S. Wickleder
(Oldenburg) 		Lanthanide Compounds with Complex Oxo-Anions: From Interesting Structural Chemistry to Useful Functionality
O 04 17:10 Henning A. Höppe,
Michel Panzer,
Karolina Kazmierczak
(Freiburg)		 Partially Ordered Mixed-Valent Rare Earth Borates
 
O 05 17:30
 		 Bassem S. Bassil,
Ulrich Kortz
(Bremen)		 Synthesis and Structural Characterization of Peroxo-Lanthanide Polyoxometalates
O 06 18:00 Thomas Harmening,
Adel Al Alam,
Samir F. Matar,
Hellmut Eckert,
Rainer Pöttgen
(Münster)
 45Sc NMR Spektroskopie an intermetallischen Verbindungen
O 07 18:20 Wilfried Hermes,
Birgit Heying,
Ute Ch. Rodewald,
Sudhindra Rayaprol,
Falko M Schappacher,
Rainer Pöttgen
(Münster)
 Struktur und Eigenschaften von GdRhZn, GdRuGe und GdPt2X (X = In, Sn)
  18:40   Terrae Rarae 2008 Award Session
Conference Dinner
Friday, December 5, 2008
Chairman: Herbert Schuhmann, Berlin
Organometallics
K 07 09:30 Marcus Rastätter,
Peter W. Roesky
(Karlsruhe)		 Bis(amido)cyclodiphosph(III)azane Complexes of Aluminum and the Rare Earth Elements
K 08 10:10 Glen Deacon
(Monash)		 New Developments in C-F Activation by Rare Earth Compounds
K 09 10:50 Peter Junk
(Monash)		 Synthesis of Lanthanoid Hydroxo cluster/Cage Complexes
  11:30   Coffee Break
O 08 12:00 Rannveig Litlabø,
Melanie Zimmermann,
Kuburat Saliu,
Josef Takats,
Karl W. Törnroos,
Reiner Anwander
(Bergen)		 A Rare-Earth Metal Variant of the Tebbe Reagent
O 09 12:20 Mathias Kramer,
Masato Ohashi,
Marcin Konkol,
Yumiko Nakajima, Thomas Spaniol,
Jun Okuda
(Aachen)		 Neutral and Cationic Molecular Lanthanoid Hydrides
 
O 10 12:40 E. Abinet,
T. P. Spaniol,
J. Okuda
(Aachen)		 h3-Allyl Complexes of the Early Lanthanides with OSSO-Type Ligands: Highly Active Catalysts in Hydrosilylation
 
  13:00   Lunch Break
Chairman: Peter Roesky, Berlin
Organometallics
K 10 14:00 Frank Edelmann
(Magdeburg)		 Multidecker Sandwich Complexes of Lanthanide Elements
K 11 14:40 Sjoerd Harder,
Christian Ruspic,
Lars Orzechowski,
Georg Jansen,
Dennis Kuchenbecker
Dirk Piesik
(Duisburg Essen)		 Insight in Bulky Metallocenes
O 11 15:20 D. T. Thielemann,
P. W. Roesky
(Karlsruhe)		 The Structural Versatility of Lanthanide-based Coordination Oligomers
O 12 15:40 Dmitrii M. Roitershtein, Mikhail E. Minyaev,
Konstantin A. Lyssenko,
Pavel A. Belyakov,
Ivan V. Glukhov,
Mikhail Yu. Antipin
(Moscow)		 Application of the Tetraphenylethylene Anion in 4f Organometallic Chemistry
  16:00   Coffee Break and Poster Session
Chairman: Koen Binnemans, Leuven
Materials
O 13 16:30 Sanjay Mathur,
Eva Hemmer
(Köln)		 Synthesis of New Precursors for the Preparation of Lanthanide-Containing Nanomaterials
O 14 16:50 Oxana Kotova,
Valentina Utochnikova,
Svetlana Eliseeva,
Sergey Samoilenkov,
Natalia Kuzmina
(Moscow)		 Gas Phase Reaction Deposition of Nonvolatile Terbium Benzoate (Tb(bz)3) Thin Films for OLEDs Application
 
O 15 17:10 Andrian P. Milanov,
Roland A. Fischer,
Anjana Devi
(Bochum)		 Synthesis, Characterization and Thermal Properties of Homoleptic Rare-Earth Guanidinates: Promising Precursors for MOCVD and ALD of Rare-Earth Oxide Thin Films
O 16 17:30 Christoph Hauser,
Clemens K. Weiss,
Nicole Jagielski,
Katharina Landfester
(Mainz)		 Lanthanide-Polymer Hybrid Nanoparticles Prepared by the Miniemulsion Technique – Design and Application
 
Saturday, December 6, 2008
Chairman: Anja Mudring, Bochum
Structure and Bonding
K 12 09:30

Mikhail V. Butovskii
Christian Döring,
Oleg L. Tok,
Frank R. Wagner,
R. Kempe
(Bayreuth)

Transition Metal – Rare Earth Bonds

 
O 17 10:10 Ahmed Yahia,
Mathias Kramer,
Jun Okuda,
Laurent Maron
(Toulouse)		 A DFT Study about Structure and Reactivity of Cationic Methyl Complexes of The Rare-Earth Metals: A Relation between Experience and Theory
O 18 10:30 Michael Seitz,
Allen G. Oliver,
Kenneth N. Raymond
(Bochum)		 The Lanthanide Contraction Revisited
 
  11:00   Coffee Break
K 13 11:30 Gerd Meyer
(Köln) 		Clusters as anti-Werner Complexes – Coordination Numbers of Endohedral Atoms
K 14 12:00 Frank R. Wagner,
Viktor Bezugly
(Dresden)		 Quantummechanical Characterization of RE-TM-Bonding Situations in Position Space
O 19 12:40 Konstin Lyssenko
(Moscow)		 Chemical Bonding Pattern in Lanthanide-Containing Systems via Topological Analysis of the Experimental Charge Density Function
  13:00   End of Conference

 

Posters

P01

Tarun K. Panda,
Frouke Aal,
Sören Randoll,
Cristian Hrib,
Thomas Bannenberg,
MatthiasTamm
(Braunschweig)

Iminofunctionalized Cyclopentadienyl- Lanthanide- and Alkaline Earth Metal- Complexes

P02

Thomas Abel,
Markus Albrecht,
Roland Fröhlich
(Aachen)

Dinuclear triple-stranded lanthanide helicates

P03

M. Ahlers,
M. S. Wickleder,
M. Ahlf,
K. Al-Shamery
(Oldenburg)

La(NO3)3 based designer precursors for deposition of ultrathin La2O3 films on semiconductor surfaces

P04

Juliane Bauer,
Axel Buchholz,
Winfried Plass
(Jena)

Building blocks for homo- and heteronuclear lanthanide assemblies

P05

B. Bielemeier,
G. Wortmann,
F. Casper,
V. Ksenofontov,
C. Felser
(Paderborn)

 Magnetic properties of GdPdSb and GdNiSb studied by 155Gd-Mössbauer spectroscopy

P06

Daniel Bojer,
Ajay Venugopal,
Ina Kamps,
Norbert W. Mitzel
(Bielefeld)

Hexacoordinated Carbon Surrounded by Electropositive Metal Atoms

P07

Fanny Bonnet,
Ana Cristina Violante,
Pascal Roussel,
André Mortreux,
Marc Visseaux
(Villeneuve d’Ascq)

A new cationic scandium hemimetallocene complex as a versatile precatalyst for selective 1,4-cis isoprene- and  syndiotactic styrene polymerizations

P08

Hasan Tahsin Bozkurt,
Claudia Wickleder
(Siegen)

Photoluminescence of RbPbCl3:Eu2+

P09

Frederick Casper,
Claudia Felser
(Mainz)

Semiconducting and half-metallic ternary rare earth compounds

P10

Joanna Cybinska,
Gerd Meyer,
Janina Legendziewicz
(Wroclaw)

A spectroscopic study of ternary potassium lanthanide chlorides doped with Pr3+ and Yb3+ ions

P11

Selvan Demir,
Gerd Meyer
(Köln)

Excision of Scandium Clusters: From the Solid State into Solution

P12

Anna-Maria Dietel,
Rhett Kempe
(Bayreuth)

Unique highly soluble aminopyridinato cerium chloride cluster through stepwise removal of coordinated THF

P13

H. Martin Dietrich,
Eberhardt Herdtweck,
Karl W. Törnroos,
Reiner Anwander
(Bergen)

Halfsandwich Bisamido Complexes of the Rare-Earth Metals: N(CHMe2)2 versus N(SiHMe2)2 Ligands

P14

Christian Döring,
Tobias Bauer,
Rhett Kempe
(Bayreuth)

Aminopyridinato ligand stabilized lanthanoid alkyl complexes and their use in isoprene polymerization

P15

Peter Dröse,
Steffen Blaurock,
Volker Lorenz
Frank T. Edelmann
(Magdeburg)

Phenyliodine(III) dichloride – An Innovative Reagent for the Synthesis of Cerium(IV) Complexes

P16

Noa K. Hangaly,
Alexander R. Petrov,
Michael Elfferding,
Jörg Sundermeyer
(Marburg)

Cyclopentadienylphosphazene Constrained Geometry Complexes of Rare-Earth Metals and their Catalytic Properties in Hydroamination Reactions

P17

Anna Getsis,
Anja-Verena Mudring
(Bochum)

Lanthanidomesogenes: [C12mim]3[LnBr6] (Ln = Tb, Dy)

P18

Elżbieta Tomaszewicz,
Małgorzata Guzik,
Joanna Cybińska,
Janina Legendziewicz
(Wroclaw)

Spectroscopic proprieties of new class tungstates; the role of codoping d-electron ions

P19

Benjamin J. Hellmann,
Norbert W. Mitzel
(Bielefeld)

Hemilabile Hydroxylamine Complexes of Rare Earth Metals and Their Earth Metal Adducts

P20

Sanjay Mathur,
Eva Hemmer,
Yvonne Kohl,
Hagen Thielecke
(Köln, St Ingbert)

Cytotoxicity of Gd(OH)3 Nanostructures prepared by Solvothermal Synthesis

P21

Nina Herzmann,
Anja-Verena Mudring,
Gerd Meyer
(Köln)

Seven-Coordinate Ruthenium in the New Praseodymium Cluster Chloride {RuPr3}Cl3

P22

Nina Herzmann,
John D. Corbett
(Köln)

New Compounds in Ternary Rare-Earth-Metal-Rich Telluride Systems: A Better Insight into the 7/2/2 System

P23

Anukul Jana,
Herbert W. Roesky
Göttingen)

New Precursor for Oxygen bridged Complexes

P24

Holger Kohlmann
(Saarbrücken)

Hydrogenation of the Laves phases Eu1-xMxMg2 (M = Sr, Ca, Sm)

P25

Michael R. Kunze,
Rudolf Taube
(Koblenz-Landau)

2,4-Dimethylpentadienyl-Komplexe des Neodyms als hochaktive Präkatalysatoren für die 1,4-cis-Butadienpolymerisation

P26

Flavie Lavoie-Cardinal,
Matthias Adlung,
Claudia Wickleder
(Siegen)

Luminescence of divalent Europium in the Perowskites MMgCl3 (M = K, Rb, Cs)

P27

Caroline Link,
Gerd Meyer
(Köln)

Two new isotypic lanthanide-silver 2D coordination polymers, Ag2Ln(Aba)4(NO3)5 (Ln=La, Nd)

P28

Pascal Link,
Uwe Ruschewitz
(Köln)

YbxCa1-xC2 : Solid solutions with interesting structural properties

P29

Chantal Lorbeer,
Anja-Verena Mudring
(Bochum)

Synthesis of EuF3-nanoparticles in ionic liquids

P30

Bert Mallik,
Anja-Verena Mudring
(Bochum)

Lanthanide containing ionic liquids

P31

Olaf Michel,
Christian Meermann,
Karl W. Törnroos,
Reiner Anwander
(Bergen)

More Parallels in Rare-Earth Metal and Alkaline Earth Metal Chemistry: A Comparative Study of MIIAlIII Peralkylated Complexes

P32

Giuseppe Montana,
Claudia Wickleder
(Siegen)

Preparation and Luminescence Properties of Ca(SCN)2:Eu2+

P33

Amadou Ndiaye,
Michael Knorr,
Michael Veith
(Saarbrücken)

NIR and Visible Luminescents Lanthanides (Ln3+)-dithiolene complexes

P34

Gennady V. Oshovsky,
Bart Hessen
(Groningen)

Selective Cross-Coupling of Aryl- and Alkyl-Acetylenes Catalyzed by Yttrocenes

P35

Sandro Pagano,
Giuseppe Montana,
Claudia Wickleder, 
Wolfgang Schnick
(München)

Synthesis of M(OCN)2 by Thermal Dissociation of M(OCN)2•Urea (M = Sr, Eu): Characterization and Luminescence study

P36

Ingo Pantenburg,
Wieland Tyrra
(Köln)

The missing solid state structures of [Y(OCOCF3)3] · 3 H2O and [Y(OCOCF2H)3(H2O)2] · H2O

P37

Isabella Römer,
Bassem S. Bassil,
Ulrich Kortz
(Bremen)

Peroxo-Cerium(IV) Containing Tungstogermanates: Synthesis, Structure and Transformation

P38

Dmitrii M. Roitershtein,
Alexander A. Vinogradov,
Alexey A. Vinogradov,
Konstantin A. Lyssenko,
Yulia V. Neliubina,
Mikhail Yu. Antipin
(Moscow)

A new insight into water-free rare-earth carboxylates. An efficient route to and structure and properties thereof

P39

Christian Ruspic,
Mattias Adlung,
Claudia Wickleder,
Sjoerd Harder
(Duisburg-Essen)

Synthesis, Structure and Physical Properties of a Superbulky Eu(II) Metallocene

P40

S. Schander,
M. S. Wickleder
(Oldenburg)

Zinc containing chloride-oxo-arsenates(III) of the lanthanides

P41

N. Schlosser,
C. Wickleder
(Siegen)

Synthesis and Luminescence Properties of Sr2Gd3(SiO4)3F doped with Eu2+ and Eu3+

P42

S. Schwarzer,
M. S. Wickleder
(Oldenburg)

Pr2(S2O7)3: The first anhydrous disulfate of a rare-earth element

P43

Jennyfer Sierau,
Gerd Meyer
(Köln)

A New Heterobimetallic Acetate:  [Dy2Co(OAc)4(H2O)2](HOAc)2

P44

Hjørdis Skår,
Yucang Liang,
N. Å. Frøystein,
Reiner Anwander
(Bergen)

Gadolinium-Functionalized Periodic Mesoporous Silica for Magnetic Resonance Imaging

P45

S. Standfuß,
Masato Ohashi,
T. P. Spaniol,
Jun Okuda
(Aachen)

Cyclen-Derived Rare-Earth Metal Hydride Complexes

P46

Nicolas Susperregui,
Laurent Maron,
Mathias Kramer,
Jun Okuda
(Toulouse)

Theoretical study of competitive Ring Opening Polymerization Initiation pathways of lactones with Yttrium based cations

P47

Oliver Thomas,
Alexander R. Petrov,
Thomas Linder,
Jörg Sundermeyer
(Marburg)

Homoleptic Tris-Aryl Complexes of the Rare Earth Metals

P48

Alexandra Trambitas,
Tarun K. Panda,
Cristian Hrib,
Thomas Bannenberg,
MatthiasTamm
(Braunschweig)

Mononuclear Lanthanide Imido Complexes

P49

Glen B. Deacon,
Peter C. Junk,
Aron Urbatsch
(Monash)

Novel Rare Earth Quinolinolate Complexes

P50

Glen B. Deacon,
Peter C. Junk,
Aron Urbatsch
(Monash)

Structural Studies On Novel Lanthanoid Pyrazolate Complexes

P51

Florian Reichart,
Kornelia Zeckert
(Leipzig)

Tris(2-pyridyl)stannyl anions and their reactivity towards lanthanides

P52

Martin Zeuner,
Frauke Hintze,
Wolfgang Schnick
(München)

A low temperature precursor approach for highly efficient spherically shaped LED-phosphors M2Si5N8:Eu2+ (M = Eu, Sr, Ba)

P53

Melanie Zimmermann,
Laura C. H. Gerber,
Karl W. Törnroos,
Reiner Anwander
(Bergen)

Organoaluminum-Assisted C–H Bond Activation: Snapshots of Nanosized Rare-Earth Metal Carbon Clusters

P54

Sina Zimmermann,
Gerd Meyer
(Köln)

The 15 Electron Magic

P55

Christoph Höller,
Alexander Zurawski,
Klaus Müller-Buschbaum
(München)

Diversity of Extreme Synthesis Routes to MOFs and COPs of the Rare Earth Elements
P56 Tamsyn Ross,
Anthony S. R. Chesman,
David R. Turner,
Glen B. Deacon,
Stuart R. Batten
(Monash)
 Approaches Towards Mixed Metal Complexes